What You Need to Know
The process relied on the NaCl solubility curve, with saturation at ~35 % w/w at 30 °C and ~39 % w/w at 100 °C. By evaporating brine in shallow ponds and then boiling at 100 °C, salt makers reduced water content and promoted crystal growth. Ash addition lowered water activity, aiding purification and removing impurities.
The Science
Primary Reaction
Evaporation and boiling of brine to precipitate NaCl crystals